Assign this Bundle to all your workstations or where needed (I am distributing it as part of the machine setup, so that every workstation has the PinItem.vbs)
Create a bundle to Pin Excel 2010 to the Taskbar and Startmenu:
IMPORTANT: you can only pin locally installed programs, this does not work for executables located on network shares.
I usually specify Schedule Type: Event / User Login under the Bundle Distribution Schedule and select "Install Immediately after Distribution" so that the bundle is active when the user login.